内容

目次

Chapter 1: Polymer Chemistry; 1.1: Basic Concepts; 1.2: The History ofthe Concept of the Macromolecule; 1.3: Classification of Polymers; 1.4:Structure and Properties of Polymers; Chapter 2: Polymerisation Reactions;2.1: Chain Polymerisation; 2.2: Arrangement of Monomer Units; 2.3: Kineticsof Chain Polymerisation; 2.4: Autoacceleration; 2.5: Practical Methods ofChain Polymerisation; 2.6: Other Chain Polymerisation Mechanisms; 2.7: StepPolymerisation; 2.8: Step polymerisation with Polyfunctional monomers; 2.9:Copolymerisation; Chapter 3: Polymer Structure; 3.1: Polymer Stereochemistry;3.2: Polymer Crystallinity; 3.3: Thermal and Mechanical Properties; Chapter4: Crosslinking; 4.1: Introduction; 4.2: Phenol-Formaldehyde Resins; 4.3:Unsaturated Polyester Resins; 4.4: Polyurethanes; 4.5: Epoxy Resins;Chapter 5: Polymer Solutions; 5.1: Introduction; 5.2: Dissolution ofPolymers; 5.3: Solubility Parameters; 5.4: Simple Liquid Mixtures andRaoult's Law; 5.5: Entropy of Mixing; 5.6: Real Molecules in Dilute Solution;5.7: Shapes of Polymer Molecules in Solution; 5.8: Reptation Model ofMolecular Motion; 5.9: Water-Soluble Polymers; 5.10: Uses of High-ViscosityPolymer Solutions; 5.11: Polymer Melts; Chapter 6: Methods of DeterminingRelative Molar Mass; 6.1: Introduction; 6.2: Molar Masses from ColligativeProperties; 6.2: .1 Vapour Phase Osmometry; 6.3: Light Scattering; 6.3: .1Experimental Determination; 6.4: Viscosity Methods of Determining RelativeMolar Mass; 6.5: End Group Analysis; 6.6: Gel Permeation Chromatography;Chapter 7: Mechanical Properties of Polymers; 7.1: Introduction; 7.2: Stress,Strain, and Young's Modulus; 7.3: Brittle and Tough Fracture; 7.4: Types ofStrength; 7.5: The Influence of Surfaces; 7.6: Viscoelasticity; 7.7: Creepand Stress Relaxation; 7.8: Cold Drawing; 7.9: Dynamic Tests; 7.10:Time/Temperature Relationship; 7.11: Rubberlike Elasticity; 7.12:Reinforced Polymers; 7.13: Practical Measurements of Mechanical Properties;7.14: Further Reading; Chapter 8: Polymer Degradation; 8.1: Introduction;8.2: Behaviour of Polymers In Fires; 8.3: Assessment of Combustion Behaviour;8.4: Improvement of Stability of Polymers in Fires; 8.5: Weathering ofPolymers; 8.6: Protection of Polymers from Photo-oxidation; 8.7: BiologicalDegradation of Polymers; 8.8: Exploitation of Polymer Degradation; Chapter 9:Dendrimers; 9.1: Introduction; 9.2: Organic Dendrimers; 9.3: SupramolecularDendrimers; 9.4: Shapes and Conformations of Dendrimers; 9.5: DendrimerMicelles; 9.6: Characterization of Dendrimers; 9.7: Applications ofDendrimers; 9.8: Megamers; Further Reading; Chapter 10 Special Topics inPolymer Chemistry; 10.1: Introduction; 10.2: Polymers in Medicine; 10.3:Ionomers; 10.4: Electronically Conducting Polymers; 10.5: InterpenetratingPolymer Networks; 10.6: Inorganic Polymers; 10.7: Polymer Liquid Crystals;10.8: Polymers for Food Packaging; Chapter 11 Polymers and the Environment;11.1: Introduction; 11.2: Pollution by Polymers; 11.3: The Nature of theProblem; 11.4: Polymers and Energy; 11.5: Recycling of Polymers; 11.6:Degradable Polymers; 11.7: The Future; Further Reading; Bibliography; SubjectIndex